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In 1993 the European Cork Industry Federation
(CELIEGE) in cooperation with the EEC undertook a detailed study of the
cork industry. The project, titled “Quercus”, combined the efforts of nine
laboratories in six countries.
The object was to identify the sources of off-flavors associated
with cork stoppers and develop a strategy to correct them.
A brief review of some of the findings presented at the Paris meeting
are shown below.
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Numerous compounds were examined as causes for off-flavors in wine. The
most prominent, 2,4,6-trichloroanisole (TCA), was determined to be present
in the majority of wines described as exhibiting a musty taint.
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Samples of “off-flavor or musty” wines exhibited the presence of TCA in
70% of the bottles analyzed. This finding corroborates a large body of
literature linking TCA to off-flavors in wine and other food products.
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A by-product of this sensory analysis was the construction of a standardized
flavor wheel that allowed the different laboratories to better coordinate
their sensory categorizations.
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With TCA identified as the major target, each individual component of the
cork processing method was examined for particular susceptibility to its
formation. The analysis has yielded a body of work that is the basis for
a protocol of recommended practices for cork manufacturers.
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The findings concluded that the single greatest correlation for TCA in
finished corks was the relative level of TCA in the original raw bark.
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A review of TCA occurrence in the forest showed a high incidence of TCA
in bark marked with the relatively rare, but easily identified condition
“yellow stain”.
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Slight increases in TCA were also found in the bark closest to the ground.
Specific precautions to avoid the high risk materials are included in the
protocol of recommended practices.
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Studies of the manufacturing process did not find specific areas that were
prone to the introduction of TCA.
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There was a conclusion that finished corks prepared with a chlorine based
wash contained significantly higher levels of residual chlorophenols. Since
one proven source of TCA is the metabolism of chlorophenols by certain
fungi the presence of chlorophenols is considered undesirable.
Studies of storage conditions were conducted under two models.
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The first tested the ability of TCA to migrate from a highly contaminated
environment through a cork stopper in a finished wine bottle. Tests did
not show any conclusive evidence of such migration even after nine months
of storage.
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The second model tested the likelihood of TCA being transmitted from a
highly contaminated environment to cork stoppers under typical warehouse
storage conditions. Tests showed that one week of storage in a highly contaminated
environment produced significant contamination. When used in bottling,
the contaminated corks “leached” TCA into the bottled wine at levels consistent
with commercial samples of tainted wines (approx. 6ppt).
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The same test was performed with wine bottles in warehouse storage conditions.
They also became contaminated after one week of storage, and when used
with clean corks, produced high TCA levels (approx. 170ppt). The difference
in relative concentration was attributed more to the relative surface areas
of the bottle compared to the cork. Industry guidelines governing storage
practices are a major focus of the study.
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The complete body of evidence will be used to prepare a protocol of manufacturing
practices that will specify techniques governing the selection and storage
of raw bark, particular manufacturing practices and final preparation and
shipping practices.
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